(or K;O) direct reaction with carbon is difficult to be carried out at the activation temperature of 730℃, indicating that they react with -CH- and -CHZ - in petroleum coke and play an activation role.The elemental potassium generated from the activation reaction intercalated and activated the petroleum coke, and the specific surface area of the activated product reached 98m'g1.XRD analysis showed that there were potassium to graphite intercalated compounds in the activated product.According to the study results of activation mechanism, the mixing of additive N can improve the dispersion of alkali and the activation of additive N at high temperature to improve the activation effect.Activated carbon with a yield of 68% and a specific surface area of 2532m'g can be obtained under the conditions of alkali-coke ratio of 3:1, activation temperature of 730℃ and activation time of 30 minutes.At the same time, the amount of hydrogen produced in the activation reaction is large, reaching 38cm'g 'min', and hydrogen can be separated and purified.activated carbon for gold
Thus, a one-step process for the preparation of activated carbon with high specific surface area was proposed.Compared with the conventional method, the process reduces the production cost, shortens the production time, saves energy, and lays a foundation for further industrial production.The prepared petroleum coke based activated carbon was used as the carrier.The catalyst supported by Ni-Mo has similar hydrodesulfurization activity with commercial catalysts. The DBT conversion rate is more than 98% at 290℃ and the catalyst has high stability.The pore size distribution of petroleum coke based activated carbon with high specific surface area is mostly between 1.0~ 2.0nm. The methane storage experiment using this sample shows that it has a high methane storage performance: at 1.4 MPa, room temperature, the mass adsorption capacity of methane is 0.112 Gg '.Electrochemical modification is to change the electrical and chemical properties of activated carbon surface by using micro electric field, so as to improve the adsorption selectivity and performance.It does not need to add chemical agents, does not need to heat, does not cause pollution to the environment, low energy consumption, only a few hundred millivolts, easy to operate.The results show that the adsorption equilibrium of activated carbon is dependent on the electric potential: the adsorption amount of activated carbon increases with the increase of the potential, and the adsorption speed is accelerated;Arpolarity polarization is beneficial to the adsorption of chloroform by activated carbon, while cathodic polarization inhibits the adsorption of chloroform by activated carbon 3-341]. Activated carbon heteroatom carrier and compound modificationActivated carbon has very high stability and good activity, these two basic properties become the activated carbon as a catalyst or catalyst carrier conditions.By introducing certain heteroatoms and compounds on the surface of activated carbon by liquid phase deposition, the adsorption performance of activated carbon can be increased by using the binding effect between these substances and adsorbents.compounds, which has the advantages of increasing the reaction rate and increasing the adsorption capacity.Yang Quanhong et al. 'Using FESO;Activated carbon material was modified.The selection of treatment technology should be based on the gas volume, purification requirements, the possibility of recovery, the economy of equipment construction and operation and other conditions. Special attention should be paid to the close cooperation with the process in practical work, so as to achieve comprehensive utilization as far as possible.activated carbon manufacturers in china
At present, there are three common methods of organic waste gas treatment at home and abroad: liquid absorption method, activated carbon adsorption method and catalytic combustion method.