The concentration of pollutants in normal production wastewater is low and can be treated by general biochemical treatment.
The maintenance sewage contains a large number of complex biodegradable substances, biodegradability is poor, for many years mainly rely on fresh water dilution treatment and combustion furnace treatment, but these two methods are low efficiency and high cost, so it is necessary to develop new wastewater treatment methods.
Although we have studied the upflow anaerobic sludge bed reactor (UASB) for the treatment of high concentration sewage of the natural gas purification plant, the start-up test results of 133 days show that the effluent COD removal rate is only about 40% when the influent COD is 6000mg/L, and the treatment effect is not good.activated carbon wholesale
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Therefore, it is of practical significance to explore and seek an effective pretreatment method.
In this paper, Fenton oxidation and activated carbon adsorption were combined to pretreat the wastewater from natural gas purification maintenance, in order to improve the subsequent operation efficiency of UASB.
This experiment by orthogonal test to determine the Fenton reagent oxidation first preliminary operating conditions, on this basis, carries on the single factor analysis method, the main factors influencing the Fenton reagent treatment effect for each study, investigation of its influence on wastewater COD removal rate, the results show that Fenton oxidation method the optimum operating conditions for natural gas purification overhaul wastewater treatment: HO2 dosing quantity 0.3 mol/L, n (HO)/n (Fe) = systematically, initial pH = 3, reaction temperature 70 ℃, reaction time, 40 min.
Under these conditions, the COD removal rate reached 78.6%, the BOD /COD value increased from 0.168 to 0.353-0.403, and the biodegradability was greatly improved.
If Ho is added in three times and the interval time is 10min, the COD removal rate will increase from 78.6% to 80.3%. Therefore, it can be seen that H0: batch addition will further improve the reaction effect.
After Fenton oxidation treatment, wastewater and activated carbon adsorption, this topic activated carbon adsorption experiments using single factor method, examines different PH, activated carbon adsorption dosing quantity and the influence of adsorption time of wastewater COD removal rate, the results show that after Fenton oxidation treatment without having to adjust PH value, according to the 20 g/L after adding the activated carbon reaction 3 h at room temperature, COD removal rate was 47.3%,, BOD/COD value of 0.438 to 0.625.
The research in this paper has laid a theoretical foundation and provided an experimental basis for the practical application of Fenton oxidation and activated carbon adsorption in the pretreatment of natural gas purification maintenance wastewater in UASB reactor.
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